Femtosecond laser-induced surface structuring of the porous transport layers in proton exchange membrane water electrolysis

verfasst von

Michel Suermann, Thomas Gimpel, Lena V. Bühre, Wolfgang Schade, Boris Bensmann, Richard Hanke-Rauschenbach

Abstract

In proton exchange membrane water electrolysis (PEMWE) cells the performance and thus the conversion efficiency are influenced by the interface between the porous transport layer (PTL) and the catalyst layer (CL). In the following paper, this interface is modified by the use of femtosecond laser-induced surface structuring, so that the specific surface area of the titanium based fibers of the PTL is increased. The resulting morphology exhibits two roughness levels of (i) a relatively coarse structure featuring tips of a few micrometers in diameter and depth, which are each covered in turn by (ii) a substructure of smaller tips of a few to several hundred nanometers in diameter and depth. PEMWE electrochemical characterization and short-term stress tests reveal that the cell performance is increased due to the laser-structuring of the PTL surface towards the CL. For instance, the cell voltage is reduced by approximately 30 mV after 100 h at 4 A cm^-2. These beneficial effects are observed over the entire current density range and thus correspond to a decreased equivalent cell resistance of at least 6 mΩ cm² for electrical interfacial contact losses and at least 2 mΩ cm² for mass transport losses. A physical characterization by scanning electron microscopy shows that the CL surface is much rougher and more jagged when using laser-structured fibers. Thus, the gaseous oxygen and the liquid water transport both from and to the active sites of the catalyst seem to be improved.

Organisationseinheit(en)

Fachgebiet Elektrische Energiespeichersysteme
Institut für Elektrische Energiesysteme

Externe Organisation(en)

Technische Universität Clausthal
Fraunhofer-Institut für Nachrichtentechnik, Heinrich-Hertz-Institut (HHI)

Typ

Artikel

Journal

Journal of Materials Chemistry A

Band

8

Seiten

4898-4910

Anzahl der Seiten

13

ISSN

2050-7488

Publikationsdatum

24.02.2020

Publikationsstatus

Veröffentlicht

Peer-reviewed

Ja

ASJC Scopus Sachgebiete

Allgemeine Chemie, Erneuerbare Energien, Nachhaltigkeit und Umwelt, Allgemeine Materialwissenschaften

Ziele für nachhaltige Entwicklung

SDG 7 – Erschwingliche und saubere Energie

Elektronische Version(en)

https://doi.org/10.1039/c9ta12127g (Zugang: Offen)