Effect of dissociation of iron-boron Pairs in crystalline silicon on solar cell properties

verfasst von
Jan Schmidt
Abstract

The effect of dissociation of interstitial iron-substitutional boron (FeiBs) pairs, as it occurs under illumination in iron-contaminated silicon solar cells, on the solar cell properties has been studied on the basis of numerical device simulations using reported recombination parameters for Fei and FeiBs. Most cell parameters are found to degrade during FeiBs dissociation. However, the open-circuit voltage can also increase within certain ranges of the iron concentration. Critical iron concentrations are determined, giving the threshold contamination level above which a significant degradation in the corresponding cell parameter can be observed. The threshold iron contamination level of the open-circuit voltage degradation is found to be up to two orders of magnitude larger than the threshold iron level of the short-circuit current degradation. As the behaviour of the cell parameters under illumination is specific to the dissociation of FeiBs pairs, the characteristic changes in the cell parameters due to illumination may be used as a simple way of identifying iron contamination problems in silicon solar cells.

Externe Organisation(en)
Institut für Solarenergieforschung GmbH (ISFH)
Typ
Artikel
Journal
Progress in Photovoltaics: Research and Applications
Band
13
Seiten
325-331
Anzahl der Seiten
7
ISSN
1062-7995
Publikationsdatum
06.2005
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Elektronische, optische und magnetische Materialien, Erneuerbare Energien, Nachhaltigkeit und Umwelt, Physik der kondensierten Materie, Elektrotechnik und Elektronik
Ziele für nachhaltige Entwicklung
SDG 7 – Erschwingliche und saubere Energie
Elektronische Version(en)
https://doi.org/10.1002/pip.594 (Zugang: Unbekannt)