Temperature-dependent contact resistance of carrier selective Poly-Si on oxide junctions

verfasst von
Nils Folchert, Michael Rienäcker, A. A. Yeo, Byungsul Min, Robby Peibst, Rolf Brendel
Abstract

Carrier selective junctions using a poly-silicon/ silicon oxide stack on crystalline silicon feature low recombination currents J0 whilst allowing for low contact resistivity ρC. We describe the limiting current transport mechanism as a combination of homogeneous tunneling through the interfacial silicon oxide layer and transport through pinholes where the interfacial silicon oxide layer is locally disrupted. We present an experimental method and its theoretical basis to discriminate between homogenous tunneling and local pinhole transport mechanisms on n + /n or p + /p junctions by measuring the temperature-dependent contact resistance. Theory predicts opposing trends for the temperature dependencies of tunneling and pinhole transport. This allows identifying the dominant transport path. For the contact resistance of two differently prepared poly-Si/ silicon oxide/ c-Si junctions we either find clear pinhole-type or clear tunneling-type temperature dependence. Pinhole transport contributes more than 94% to the total current for the sample with a 2.1 nm-thick interfacial silicon oxide that we anneal at a temperature of 1050 °C to achieve highest selectivity. In contrast pinhole transport contributes less than 35 % to the total current for the sample with a 1.7 nm-thick silicon oxide that we annealed at only 700 °C in order to avoid pinholes.

Organisationseinheit(en)
Institut für Materialien und Bauelemente der Elektronik
Institut für Festkörperphysik
Externe Organisation(en)
Institut für Solarenergieforschung GmbH (ISFH)
Typ
Artikel
Journal
Solar Energy Materials and Solar Cells
Band
185
Seiten
425-430
Anzahl der Seiten
6
ISSN
0927-0248
Publikationsdatum
10.2018
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Elektronische, optische und magnetische Materialien, Erneuerbare Energien, Nachhaltigkeit und Umwelt, Oberflächen, Beschichtungen und Folien
Ziele für nachhaltige Entwicklung
SDG 7 – Erschwingliche und saubere Energie
Elektronische Version(en)
https://doi.org/10.1016/j.solmat.2018.05.046 (Zugang: Geschlossen)