On the chances and challenges of combining electron-collecting nPOLO and hole-collecting Al-p⁺ contacts in highly efficient p-type c-Si solar cells

verfasst von

Robby Peibst, Felix Haase, Byungsul Min, Christina Hollemann, Till Brendemühl, Karsten Bothe, Rolf Brendel

Abstract

ISFH is following a distinct cell development roadmap, which comprises—as a short-term concept—the combination of an n-type doped electron-collecting poly-Si on oxide (POLO) junction with an Al-alloyed p⁺ junction for hole collection. This combination can be integrated either in front- and back-contacted back junction cells (POLO-BJ) or in interdigitated back-contacted cells (POLO-IBC). Here, we present recent progress with these two cell concepts. We report on a certified M2-sized 22.9% efficient POLO-BJ cell with a temperature coefficient TC_η of only −(0.3 ± 0.02) %_rel/K and a certified 23.7% (4 cm² d.a.) efficient POLO-IBC cell. We discuss various specific conceptual aspects of this technology and present a simulation-based sensitivity analysis for quantities related to the quality of the hole-collecting alloyed Al-p⁺ junction which are subject to continuous improvement and thus hard to predict exactly. We report that the measured pseudo fill factor values decrease more due to metallization than would be expected from recombination in the metallized regions with an ideality factor of one only. The gap to pseudo fill factor values that are theoretically achievable at the respective open-circuit voltages is 1.1%_abs (Ga-doped wafer) for POLO-IBC and 1.4%_abs (B-doped wafer) to 2%_abs (Ga-doped wafer) for POLO-BJ. With an embedded blocking layer for Ag crystallites in the poly-Si, we present a concept to reduce this gap.

Organisationseinheit(en)

Institut für Materialien und Bauelemente der Elektronik
Abt. Solarenergie

Externe Organisation(en)

Institut für Solarenergieforschung GmbH (ISFH)

Typ

Artikel

Journal

Progress in Photovoltaics: Research and Applications

Band

31

Seiten

327-340

Anzahl der Seiten

14

ISSN

1062-7995

Publikationsdatum

01.03.2023

Publikationsstatus

Veröffentlicht

Peer-reviewed

Ja

ASJC Scopus Sachgebiete

Elektronische, optische und magnetische Materialien, Erneuerbare Energien, Nachhaltigkeit und Umwelt, Physik der kondensierten Materie, Elektrotechnik und Elektronik

Ziele für nachhaltige Entwicklung

SDG 7 – Erschwingliche und saubere Energie

Elektronische Version(en)

https://doi.org/10.1002/pip.3545 (Zugang: Offen)